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Hydrotreating of light gas oil using a NiMo catalyst supported on activated carbon produced from fluidpetroleum coke

N. Rambabu,Sandeep Badoga,Kapil K. Soni,A.K. Dalai,J. Adjaye

《化学科学与工程前沿（英文）》 2014年 第8卷 第2期   页码 161-170 doi: 10.1007/s11705-014-1430-1

摘要： Nitric acid functionalized steam activated carbon (NAFSAC) was prepared from waste fluid petroleum coke (FPC) and used as a support material for the synthesis of a NiMo catalyst (2.5 wt-% Ni and 13 wt-% Mo). The catalyst was then used for the hydrotreatment of light gas oil. The support and catalysts were characterized by Brunauer-Emmett-Teller (BET) gas adsorption method, X-ray diffraction, H -temperature programmed reduction, NH -temperature programmed desorption, CO-chemisorption, mass spetrography, scanning electron microscopy (SEM), Boehm titration, and Fourier transform infrared spectroscopy (FTIR). The SEM results showed that the carbon material retained a needle like structure after functionalization with HNO . The Boehm titration, FTIR, and BET results confirmed that the HNO functionalized material had moderate acidity, surface functional groups, and mesoporosity respectively. The produced NAFSAC had an inert nature, exhibited the sink effect and few metal support interactions, and contained functional groups. All of which make it a suitable support material for the preparation of a NiMo hydrotreating catalyst. Hydrotreating activity studies of the NiMo/NAFSAC catalyst were carried out under industrial operating conditions in a laboratory trickle bed reactor using coker light gas oil as the feedstock. A parallel study was performed on the hydrotreating activity of NiMo/ -Al O as a reference catalyst. The hydrodesulfurization and hydrodenitrogenation activities of the NiMo/NAFSAC catalyst were 62% and 30%, respectively.

关键词： activated carbon     fluid petroleum coke     NiMo catalyst     hydrotreating     light gas oil    

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Comparison of combustion characteristics of petroleum coke and coal in one-dimensional furnace

Qulan ZHOU, Qinxin ZHAO, Guangjie ZHOU, Huiqing WANG, Tongmo XU, Shien HUI,

《能源前沿（英文）》 2010年 第4卷 第3期   页码 436-442 doi: 10.1007/s11708-009-0059-0

摘要： The effect of primary air fraction , outer secondary air swirl strength and excess oxygen coefficient on the combustion characteristics of petroleum coke, Hejin lean coal and Shenmu soft coal are researched on a one-dimensional furnace using a dual channel swirl burner. The results show that with the increase in primary air fraction , the NO emission concentrations of both Hejin lean coal and petroleum coke increase, and the combustion worsens in the earlier stage, but the burn-out rate of Shenmu soft coal is improved. The NO emission concentration obtains a minimum value with an increase in . The ignition and burn-out rate of petroleum coke and Shenmu soft coal are optimal when Ω is minimum and Ω=0.87, respectively. However, both the NO emission concentration of petroleum coke and Shenmu soft coal are minimum when Ω=1.08. The increase in excess oxygen coefficient delays the ignition of petroleum coke, worsens the combustion condition and increases the NO emission concentration, but it greatly decreases the NO emission concentration of Shenmu soft coal.

关键词： petroleum coke     Shenmu soft coal     Hejin lean coal     combustion characteristics     experimental research    

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Refrigeration cycle for cryogenic separation of hydrogen from coke oven gas

CHANG Kun, LI Qiang

《能源前沿（英文）》 2008年 第2卷 第4期   页码 484-488 doi: 10.1007/s11708-008-0096-0

摘要： Ten billion cubic meters of hydrogen are dissipated to the environment along with the emission of coke-oven gas every year in China. A novel cryogenic separation of hydrogen from coke oven gas is proposed to separate the hydrogen and liquefy it simultaneously, and the cooling capacity is supplied by two refrigeration cycles. The performance of the ideal vapor refrigeration cycle is analyzed with methane and nitrogen as refrigerant respectively. The results show that the coefficient of performance (COP) of methane refrigeration cycle is 2.7 times that of nitrogen refrigeration cycle, and the figure of merit (FOM) of methane refrigeration cycle is 1.6 times that of nitrogen refrigeration cycle. The performance of ideal gas refrigeration cycle is also analyzed with neon, hydrogen and helium as refrigerant respectively. The results show that both the coefficient of performance and figure of merit of neon refrigeration cycle is the highest. It is thermodynamically possible to arrange the refrigeration cycle with methane and neon as refrigerant, respectively.
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Optimal slot dimension for skirt support structure of coke drums

Edward WANG, Zihui XIA

《机械工程前沿（英文）》 2018年 第13卷 第4期   页码 554-562 doi: 10.1007/s11465-018-0513-y

摘要：

The skirt-to-shell junction weld on coke drums is susceptible to fatigue failure due to severe thermal cyclic stresses. One method to decrease junction stress is to add slots near the top of the skirt, thereby reducing the local stiffness close to the weld. The most common skirt slot design is thin relative to its circumferential spacing. A new slot design, which is significantly wider, is proposed. In this study, thermal-mechanical elastoplastic 3-D finite element models of coke drums are created to analyze the effect of different skirt designs on the stress/strain field near the shell-to-skirt junction weld, as well as any other critical stress locations in the overall skirt design. The results confirm that the inclusion of the conventional slot design effectively reduces stress in the junction weld. However, it has also been found that the critical stress location migrates from the shell-to-skirt junction weld to the slot ends. A method is used to estimate the fatigue life near the critical areas of each skirt slot design. It is found that wider skirt slots provide a significant improvement on fatigue life in the weld and slot area.

关键词： coke drum     stress analysis     cyclic stress     fatigue life     skirt slots    

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Optimization of process parameters for preparation of powdered activated coke to achieve maximum SO

Binxuan ZHOU, Tao WANG, Tianming XU, Cheng LI, Yuan ZHAO, Jiapeng FU, Zhen ZHANG, Zhanlong SONG, Chunyuan MA

《能源前沿（英文）》 2021年 第15卷 第1期   页码 159-169 doi: 10.1007/s11708-020-0719-7

摘要： Powdered activated coke (PAC) is a good adsorbent of SO , but its adsorption capacity is affected by many factors in the preparation process. To prepare the PAC with a high SO adsorption capacity using JJ-coal under flue gas atmosphere, six parameters (oxygen-coal equivalent ratio, reaction temperature, reaction time, O concentration, CO concentration, and H O concentration) were screened and optimized using the response surface methodology (RSM). The results of factor screening experiment show that reaction temperature, O concentration, and H O (g) concentration are the significant factors. Then, a quadratic polynomial regression model between the significant factors and SO adsorption capacity was established using the central composite design (CCD). The model optimization results indicate that when reaction temperature is 904.74°C, O concentration is 4.67%, H O concentration is 27.98%, the PAC (PAC-OP) prepared had a higher SO adsorption capacity of 68.15 mg/g while its SO adsorption capacity from a validation experiment is 68.82 mg/g, and the error with the optimal value is 0.98%. Compared to two typical commercial activated cokes (ACs), PAC-OP has relatively more developed pore structures, and its and are 349 m /g and 0.1475 cm /g, significantly higher than the 186 m /g and 0.1041 cm /g of AC1, and the 132 m /g and 0.0768 cm /g of AC2. Besides, it also has abundant oxygen-containing functional groups, its surface O content being 12.09%, higher than the 10.42% of AC1 and 10.49% of AC2. Inevitably, the SO adsorption capacity of PAC-OP is also significantly higher than that of both AC1 and AC2, which is 68.82 mg/g versus 32.53 mg/g and 24.79 mg/g, respectively.

关键词： powdered activated coke (PAC)     SO2 adsorption capacity     parameters optimization     response surface methodology    

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Formation of coke in thermal cracking of jet fuel under supercritical conditions

ZHU Yuhong, YU Caixiang, LI Zimu, MI Zhentao, ZHANG Xiangwen

《化学科学与工程前沿（英文）》 2008年 第2卷 第1期   页码 17-21 doi: 10.1007/s11705-008-0024-1

摘要： Continuous-flow reactor experiments were carried out to study coke formation from thermal cracking of home-made jet fuel RP-3 under supercritical conditions. The mechanism and precursor of coke forming were analyzed. The starting cracking temperature of RP-3 fuel was determined to be 471.8°C by differential scanning calorimetry (DSC). Temperature-programmed oxidation and scanning electron microscopy (SEM) characterizations of the stressed tubes showed that there are three different coke species including chemisorbed carbon, amorphous carbon and filamentous coke in the solid deposits. More than 90% of coke deposits are carried away by the supercritical fluid, which has strong capabilities of extraction for coke deposits and their precursors. There were 17.1 wt-% of iron and 11.1 wt-% of chromium found on the coke surface detected by energy dispersive spectroscopy (EDS) which suggests carburetion on alloy. RP-3 fuel and its cracking liquids were analyzed by GC-MS,which showed that the content of alkyl benzene and alkyl naphthalene increased evidently in cracking liquids.

关键词： dispersive spectroscopy     different     extraction     calorimetry     filamentous    

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Persistent Integration and Innovation Management Mode and Its Applications in Petroleum Production Engineering

He Liu

《工程管理前沿（英文）》 2015年 第2卷 第4期   页码 339-343 doi: 10.15302/J-FEM-2015055

摘要： This paper proposes a new management mode named the persistent integration and innovation management mode to satisfy the requirements by the fast development at oilfields. Taking engineering philosophy as the guidance and technical innovations in petroleum production engineering as the breaking point, the management mode combines long term production practice at oilfields with modern management methods. The management mode integrates intellectuals, techniques, capital, and information and so on to accomplish global optimization of resource configuration. Sets of new techniques, new methods, new technologies and new equipment in petroleum production engineering have been proposed under the guidance of the management mode, achieving great social and economic benefits.

关键词： integration and innovation     engineering philosophy     petroleum production engineering     Daqing Oilfield    

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Sensitivity analysis of a methanol and power polygeneration system fueled with coke oven gas and coal

Guoqiang ZHANG, Lin GAO, Hongguang JIN, Rumou LIN, Sheng LI

《化学科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 491-497 doi: 10.1007/s11705-010-0511-z

摘要： The sensitivity analysis of a polygeneration energy system fueled with duo fuel of coke oven gas and coal gas is performed in the study, and the focus is put on the relations among syngas composition, conversation rate and performance. The impacts of the system configuration together with the fuel composition on the performance are investigated and discussed from the point of cascading utilization of fuel chemical energy. First, the main parameters affecting the performance are derived along with the analysis of the system configuration and the syngas composition. After the performance is being simulated by means of the Aspen Plus process simulator of version 11.1, the variation of the performance due to the composition of syngas and the conversion rate of chemical subsystem is obtained and discussed. It is obtained from the result that the proper conversion rate of the chemical subsystem according to the specific syngas composition results in better performance. And the syngas composition affects the optimal conversion rate of the chemical subsystem, the optimal point of which is around the stoichiometric composition for methanol production (CO/H = 0.5). In all, the polygeneration system fueled with coke oven gas and coal gas, which can realize the reasonable conversion of syngas to power and chemical product according to the syngas composition, is a promising method for coal energy conversion and utilization.

关键词： duo fuel of coke oven gas and coal gas     polygeneration of power and methanol     sensitivity analysis     the relation among energy utilization     syngas composition and chemical conversion rate    

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Effect of oil shale semi-coke on deposit mineralogy and morphology in the flue path of a CFB burning

Zhuo LIU, Jianbo LI, Mingming ZHU, Xiaofeng LU, Zhezi ZHANG, Dongke ZHANG

《能源前沿（英文）》 2021年 第15卷 第1期   页码 26-37 doi: 10.1007/s11708-020-0668-1

摘要： The effect of oil shale semi-coke (SC) on the mineralogy and morphology of the ash deposited on probes situated in the flue path of a circulating fluidized bed (CFB) which burns Zhundong lignite (ZD) was investigated. 10 wt% or 20 wt% SC was added to ZD, which were then combusted in the CFB furnace at 950°C. Two probes with vertical and horizontal orientations were installed in the flue duct to simulate ash deposition. Both windward and leeward ash deposits on probes (P W, P L, P W and P L) were analyzed by using a scanning electron microscopy with energy dispersive X-ray (SEM-EDX), X-ray diffraction (XRD), an inductively coupled plasma optical emission spectrometry ICP-OES, and a particle size analyzer. When ZD was burned alone, the P W deposit was comprised of agglomerates (<30 m) enriched in CaSO and Na SiO , incurring significant sintering. The P L and P W deposits, however, were of both discrete and agglomerated particles in similar mineral phases but with coarser sizes. The P L deposit was mainly fine ash particles where Na SiO and Na SO were absent. As SC was added, the agglomerates in both P W and P L decreased. Moreover, SiO and Ca/Na aluminosilicates dominated the mineral phases whereas Na SiO and Na SO disappeared, showing a decrease in deposit stickiness. Likewise, the P W deposit was found less spread on the probe, decreasing its deposition propensity. Na-bearing minerals turned into (Na, K)(Si Al)O and (Ca, Na)(Si, Al) O in the P W deposit. Moreover, Na in the deposits decreased from 32 mg/g to less than 15 mg/g as SC presented. The addition of SC would therefore help alleviate the propensity of ash deposition in the flue path in the CFB combustion of ZD.

关键词： ash deposition     circulating fluidized bed (CFB)     mineral transformation     oil shale semi-coke (SC)     Zhundong lignite (ZD)    

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Review of the LNG intermediate fluid vaporizer and its heat transfer characteristics

《能源前沿（英文）》 2022年 第16卷 第3期   页码 429-444 doi: 10.1007/s11708-021-0747-y

摘要： The intermediate fluid vaporizer (IFV), different from other liquefied natural gas (LNG) vaporizers, has many advantages and has shown a great potential for future applications. In this present paper, studies of IFV and its heat transfer characteristics in the LNG vaporization unit E2 are systematically reviewed. The research methods involved include theoretical analysis, experimental investigation, numerical simulation, and process simulation. First, relevant studies on the overall calculation and system design of IFV are summarized, including the structural innovation design, the thermal calculation model, and the selection of different intermediate fluids. Moreover, studies on the fluid flow and heat transfer behaviors of the supercritical LNG inside the tubes and the condensation heat transfer of the intermediate fluid outside the tubes are summarized. In the thermal calculations of the IFV, the selections of the existing heat transfer correlations about the intermediate fluids are inconsistent in different studies, and there lacks the accuracy evaluation of those correlations or comparison with experimental data. Furthermore, corresponding experiments or numerical simulations on the cryogenic condensation heat transfer outside the tubes in the IFV need to be further improved, compared to those in the refrigeration and air-conditioning temperature range. Therefore, suggestions for further studies of IFV are provided as well.

关键词： intermediate fluid vaporizer     design of structure and intermediate fluid     condensation heat transfer    

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Smart oilfield development and transition of petroleum-based cities

He LIU, Xinhua MA

《工程管理前沿（英文）》 2019年 第6卷 第2期   页码 299-301 doi: 10.1007/s42524-019-0024-5

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Review of fluid and control technology of hydraulic wind turbines

Maolin CAI, Yixuan WANG, Zongxia JIAO, Yan SHI

《机械工程前沿（英文）》 2017年 第12卷 第3期   页码 312-320 doi: 10.1007/s11465-017-0433-2

摘要：

This study examines the development of the fluid and control technology of hydraulic wind turbines. The current state of hydraulic wind turbines as a new technology is described, and its basic fluid model and typical control method are expounded by comparing various study results. Finally, the advantages of hydraulic wind turbines are enumerated. Hydraulic wind turbines are expected to become the main development direction of wind turbines.

关键词： wind turbine     hydraulic system     fluid model     control technology    

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Computational fluid dynamics simulation of aerosol transport and deposition

Yingjie TANG, Bing GUO

《环境科学与工程前沿（英文）》 2011年 第5卷 第3期   页码 362-377 doi: 10.1007/s11783-011-0365-8

摘要： In this article computational fluid dynamics (CFD) simulation of aerosol transport and deposition, i.e. the transport and deposition of particles in an aerosol, is reviewed. The review gives a brief account of the basics of aerosol mechanics, followed by a description of the general CFD approach for flow field simulation, turbulence modeling, wall treatments and simulation of particle motion and deposition. Then examples from the literature are presented, including CFD simulation of particle deposition in human respiratory tract and particle deposition in aerosol devices. CFD simulation of particle transport and deposition may provide information that is difficult to obtain through physical experiments, and it may help reduce the number of experiments needed for device design. Due to the difficulty of describing turbulent flow and particle-eddy interaction, turbulent dispersion of particles remains one of the greatest challenges for CFD simulation. However, it is possible to take a balanced approach toward quantitative description of aerosol dispersion using CFD simulation in conjunction with empirical relations.

关键词： computational fluid dynamics (CFD)     aerosol     transport     deposition    

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Investigation of carbon dioxide photoreduction process in a laboratory-scale photoreactor by computational fluid

《化学科学与工程前沿（英文）》 2022年 第16卷 第7期   页码 1149-1163 doi: 10.1007/s11705-021-2096-0

摘要： The production of solar fuels via the photoreduction of carbon dioxide to methane by titanium oxide is a promising process to control greenhouse gas emissions and provide alternative renewable fuels. Although several reaction mechanisms have been proposed, the detailed steps are still ambiguous, and the limiting factors are not well defined. To improve our understanding of the mechanisms of carbon dioxide photoreduction, a multiphysics model was developed using COMSOL. The novelty of this work is the computational fluid dynamic model combined with the novel carbon dioxide photoreduction intrinsic reaction kinetic model, which was built based on three-steps, namely gas adsorption, surface reactions and desorption, while the ultraviolet light intensity distribution was simulated by the Gaussian distribution model and Beer-Lambert model. The carbon dioxide photoreduction process conducted in a laboratory-scale reactor under different carbon dioxide and water moisture partial pressures was then modeled based on the intrinsic kinetic model. It was found that the simulation results for methane, carbon monoxide and hydrogen yield match the experiments in the concentration range of 10−4 mol·m–3 at the low carbon dioxide and water moisture partial pressure. Finally, the factors of adsorption site concentration, adsorption equilibrium constant, ultraviolet light intensity and temperature were evaluated.

关键词： carbon dioxide photoreduction     computational fluid dynamic simulation     kinetic model     Langmuir adsorption    

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Visbreaking of heavy petroleum oil catalyzed by SO/ZrO solid super-acid doped with Ni or Sn

JING Ping, LI Qingbiao, HAN Mei, SUN Daohua, JIA Lishan, FANG Weiping

《化学科学与工程前沿（英文）》 2008年 第2卷 第2期   页码 186-190 doi: 10.1007/s11705-008-0035-y

摘要： SO/ZrO solid super-acid catalysts (SZ) doped with Ni or Sn (Ni/SZ, Sn/SZ) were prepared for catalytic visbreaking of heavy petroleum oil from Shengli oil field. The visbreaking reactions were carried out at 240°C and 3–4 MPa for 24 h using a heavy petroleum oil to catalyst mass ratio of 100 : 0.05. The effect of water content on viscosity of heavy petroleum oil was also investigated. Both catalysts can promote thermolysis of heavy petroleum oil and the viscosity was reduced from 0.319 Pa·s to 0.135 Pa·s for Ni/SZ and 0.163 Pa·s for (Sn/SZ) with visbreaking rates of 57.7% and 48.9%, respectively. After visbreaking, the saturated hydrocarbon content increased while aromatics, resin, asphaltene, sulfur and nitrogen content decreased. The presence of water was disadvantageous to visbreaking of heavy petroleum oil.

关键词： thermolysis     Shengli     asphaltene     SO/ZrO     presence    

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标题 作者 时间 类型 操作

Hydrotreating of light gas oil using a NiMo catalyst supported on activated carbon produced from fluidpetroleum coke

N. Rambabu,Sandeep Badoga,Kapil K. Soni,A.K. Dalai,J. Adjaye

期刊论文

Comparison of combustion characteristics of petroleum coke and coal in one-dimensional furnace

Qulan ZHOU, Qinxin ZHAO, Guangjie ZHOU, Huiqing WANG, Tongmo XU, Shien HUI,

期刊论文

Refrigeration cycle for cryogenic separation of hydrogen from coke oven gas

CHANG Kun, LI Qiang

期刊论文

Optimal slot dimension for skirt support structure of coke drums

Edward WANG, Zihui XIA

期刊论文

Optimization of process parameters for preparation of powdered activated coke to achieve maximum SO

Binxuan ZHOU, Tao WANG, Tianming XU, Cheng LI, Yuan ZHAO, Jiapeng FU, Zhen ZHANG, Zhanlong SONG, Chunyuan MA

期刊论文

Formation of coke in thermal cracking of jet fuel under supercritical conditions

ZHU Yuhong, YU Caixiang, LI Zimu, MI Zhentao, ZHANG Xiangwen

期刊论文

Persistent Integration and Innovation Management Mode and Its Applications in Petroleum Production Engineering

He Liu

期刊论文

Sensitivity analysis of a methanol and power polygeneration system fueled with coke oven gas and coal

Guoqiang ZHANG, Lin GAO, Hongguang JIN, Rumou LIN, Sheng LI

期刊论文

Effect of oil shale semi-coke on deposit mineralogy and morphology in the flue path of a CFB burning

Zhuo LIU, Jianbo LI, Mingming ZHU, Xiaofeng LU, Zhezi ZHANG, Dongke ZHANG

期刊论文

Review of the LNG intermediate fluid vaporizer and its heat transfer characteristics

期刊论文

Smart oilfield development and transition of petroleum-based cities

He LIU, Xinhua MA

期刊论文

Review of fluid and control technology of hydraulic wind turbines

Maolin CAI, Yixuan WANG, Zongxia JIAO, Yan SHI

期刊论文

Computational fluid dynamics simulation of aerosol transport and deposition

Yingjie TANG, Bing GUO

期刊论文

Investigation of carbon dioxide photoreduction process in a laboratory-scale photoreactor by computational fluid

期刊论文

Visbreaking of heavy petroleum oil catalyzed by SO/ZrO solid super-acid doped with Ni or Sn

JING Ping, LI Qingbiao, HAN Mei, SUN Daohua, JIA Lishan, FANG Weiping

期刊论文